INSERT INTO cscart_cp_web_images_for_change (`image_path`, `webp_path`) 
VALUES 
  (
    'detailed/9/LES_PLAIN_col.01_квадрат.jpg', 
    'detailed/9/3645213455.webp'
  ) ON DUPLICATE KEY 
UPDATE 
  `image_path` = 'detailed/9/LES_PLAIN_col.01_квадрат.jpg', 
  `webp_path` = 'detailed/9/3645213455.webp'